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Haloalkanes and Haloarenes

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CBSE Class 12th (Haloalkanes and Haloarenes) Full 04 Video Lectures

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Haloalkanes and Haloarenes | Part #1 | NEET | Class 12th Chemistry Video Lecture | Updated Course

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Haloalkanes and Haloarenes | Part #2 | NEET | Class 12th Chemistry Video Lecture | Updated Course

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Haloalkanes and Haloarenes | Part #3 | NEET | Class 12th Chemistry Video Lecture | Updated Course

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Haloalkanes and Haloarenes | Part #4 | NEET | Class 12th Chemistry Video Lecture | Updated Course

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Haloalkanes and Haloarenes Class 12 NEET Chemistry

Chapter 10 Haloalkanes and Haloarenes Class 12 NEET Chemistry deals with:

- Halo alkanes are the compounds containing halogen atom attached to the sp3 hybridized carbon atom of an alkyl group.
- Haloarenes are the compounds containing halogen atom attached to sp2 hybridized carbon atom of an aryl group.
- Classification of halo alkanes and halo arenes On the Basis of number of halogen atoms
- Depending on number of halogen atoms present in halo alkanes and halo arenes they can be classified as mono (one atom), di (two atoms), or Polyhalogen (tri- (three atoms), tetra- (four atoms), etc.) compounds.

Classification of halo alkanes and halo arenes on the basis of compounds containing sp³C—X Bond

(a) Alkyl halides or halo alkanes (R—X)

They create a homologous series represented by CnH2n+1X and can be further classified as primary, secondary or tertiary.

(b) Allylic halides

The compounds with halogen atoms bonded to sp3-hybridised carbon to carbon-carbon double bond (C=C) i.e. to an allylic carbon.

The halogen atom of these compounds is bonded to sp3-hybridised carbon atom placed next to an aromatic ring.

Classification of halo alkanes and halo arenes on the basis of compounds containing sp² c—x bond

(a) Vinylic halides

The halogen atom of these compounds is bonded to sp2-hybridised carbon atom of a carbon-carbon double bond (C = C).

(b) Aryl halides

The halogen atom of these compounds is bonded to the sp2-hybridised carbon atom of an aromatic ring.

Nomenclature

Nomenclature of halo alkanes
Select the longest chain of carbon that contains the halogen atom.
Give least possible number to the halogen atom.
The carbon containing double or triple bond is given the least number.
Place the suitable suffix like di, tri, tetra for 2, 3, 4 halogen atoms respectively.
Name the compounds as halo alkanes, halo alkenes or halo alkynes.

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